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  1. ABSTRACT WASP-12 b is an ultra-hot Jupiter of special interest for atmospheric studies since it is on an inspiraling orbit in an extreme environment of intense radiation and circumstellar gas. Previously claimed detections of active mass-loss from this planet are controversial across the literature. To address this controversy, we obtain two new transit observations of WASP-12 b with the optical high-resolution PEPSI spectrograph on the Large Binocular Telescope. Contrary to previous work, we do not observe planetary H$$\alpha$$ absorption and rule out the amplitude of previously reported detections. Our non-detection may be limited by the sensitivity of our data or could indicate weaker mass-loss than suggested by previous studies. We conduct injection-recovery experiments to place constraints on the radial extent of WASP-12 b’s escaping atmosphere as probed by Balmer lines, but find that our data do not have the sensitivity to probe down to the planet’s Roche lobe. Using physically motivated models of atmospheric escape, we explore upper limit constraints on the planet’s mass-loss rate and deem the data quality in the wavelength regime of Balmer lines insufficient to determine a physically meaningful constraint. We also conduct a spectral survey of other optical absorbers to trace atmospheric circulation but detect no additional absorption. We conclude that previous claims of H$$\alpha$$ absorption from the atmosphere of WASP-12 b should be reevaluated. Given the anticipated line strength of Balmer/optical features, observing the atmosphere of this faint target will require stacking more observations even with the largest telescope facilities available. 
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  2. Diffraction-limited radial-velocity instruments offer a pathway towards improved precision and stability, and the exploration of new parameter spaces at high spatial and spectral resolution. However, achieving the necessary performance requires careful instrument design and considerable on-sky testing. We describe the design and construction of ‘Little iLocater’ (Lili), a compact spectrograph that has been used to validate the performance of the front-end fibre-injection system of the iLocater spectrograph. We present the design, assembly, and performance using on-sky data obtained at the Large Binocular Telescope (LBT), including extraction of spectra from standard stars, testing of the atmospheric dispersion corrector to elevations of 40°, and spatially resolved spectra from close companion systems. These results show the front-end fibre-injection system is performing as expected and is indicative of iLocater’s capabilities once installed at the LBT. 
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  3. Precision radial velocity spectrographs that use adaptive optics (AO) show promise to advance telescope observing capabilities beyond those of seeing-limited designs. We are building a spectrograph for the Large Binocular Telescope (LBT) named iLocater that uses AO to inject starlight directly into single mode fibers. iLocater's first acquisition camera system (the SX camera), which receives light from one of the 8.4 m diameter primary mirrors of the LBT, was initially installed in summer 2019 and has since been used for several commissioning runs. We present results from first-light observations that include on-sky measurements as part of commissioning activities. Imaging measurements of the bright B3IV star 2 Cygni (V= 4.98) resulted in the direct detection of a candidate companion star at an angular separation of onlyθ = 70 mas. Follow-up AO measurements using Keck/NIRC2 recover the candidate companion in multiple filters. AnR ≈ 1500 miniature spectrograph recently installed at the LBT named Lili provides spatially resolved spectra of each binary component, indicating similar spectral types and strengthening the case for companionship. Studying the multiplicity of young runaway star systems like 2 Cygni (36.6 ± 0.5 Myr) can help to understand formation mechanisms for stars that exhibit anomalous velocities through the Galaxy. This on-sky demonstration illustrates the spatial resolution of the iLocater SX acquisition camera working in tandem with the LBT AO system; it further derisks a number of technical hurdles involved in combining AO with Doppler spectroscopy. 
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  4. ABSTRACT Most ultra-hot Jupiters (UHJs) show evidence of temperature inversions, in which temperature increases with altitude over a range of pressures. Temperature inversions can occur when there is a species that absorbs the stellar irradiation at a relatively high level of the atmospheres. However, the species responsible for this absorption remains unidentified. In particular, the UHJ KELT-20b is known to have a temperature inversion. Using high resolution emission spectroscopy from LBT/PEPSI we investigate the atomic and molecular opacity sources that may cause the inversion in KELT-20b, as well as explore its atmospheric chemistry. We confirm the presence of Fe i with a significance of 17σ. We also report a tentative 4.3σ detection of Ni i. A nominally 4.5σ detection of Mg i emission in the PEPSI blue arm is likely in fact due to aliasing between the Mg i cross-correlation template and the Fe i lines present in the spectrum. We cannot reproduce a recent detection of Cr i, while we do not have the wavelength coverage to robustly test past detections of Fe ii and Si i. Together with non-detections of molecular species like TiO, this suggests that Fe i is likely to be the dominant optical opacity source in the dayside atmosphere of KELT-20b and may be responsible for the temperature inversion. We explore ways to reconcile the differences between our results and those in literature and point to future paths to understand atmospheric variability. 
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  5. We report the discovery of TOI-4641b, a warm Jupiter transiting a rapidly rotating F-type star with a stellar effective temperature of 6560 K. The planet has a radius of 0.73 RJup, a mass smaller than 3.87 MJup(3σ), and a period of 22.09 d. It is orbiting a bright star (V=7.5 mag) on a circular orbit with a radius and mass of 1.73 R⊙ and 1.41 M⊙. Follow-up ground-based photometry was obtained using the Tierras Observatory. Two transits were also observed with the Tillinghast Reflector Echelle Spectrograph, revealing the star to have a low projected spin-orbit angle (λ=$$1.41^{+0.76}_{-0.76}$$°). Such obliquity measurements for stars with warm Jupiters are relatively few, and may shed light on the formation of warm Jupiters. Among the known planets orbiting hot and rapidly rotating stars, TOI-4641b is one of the longest period planets to be thoroughly characterized. Unlike hot Jupiters around hot stars which are more often misaligned, the warm Jupiter TOI-4641b is found in a well-aligned orbit. Future exploration of this parameter space can add one more dimension to the star–planet orbital obliquity distribution that has been well sampled for hot Jupiters. 
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  6. Abstract Recent observations have shown that the atmospheres of ultrahot Jupiters (UHJs) commonly possess temperature inversions, where the temperature increases with increasing altitude. Nonetheless, which opacity sources are responsible for the presence of these inversions remains largely observationally unconstrained. We used LBT/PEPSI to observe the atmosphere of the UHJ KELT-20 b in both transmission and emission in order to search for molecular agents which could be responsible for the temperature inversion. We validate our methodology by confirming a previous detection of Feiin emission at 16.9σ. Our search for the inversion agents TiO, VO, FeH, and CaH results in non-detections. Using injection-recovery testing we set 4σupper limits upon the volume mixing ratios for these constituents as low as ∼1 × 10−9for TiO. For TiO, VO, and CaH, our limits are much lower than expectations from an equilibrium chemical model, while we cannot set constraining limits on FeH with our data. We thus rule out TiO and CaH as the source of the temperature inversion in KELT-20 b, and VO only if the line lists are sufficiently accurate. 
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  8. Abstract JWST has ushered in an era of unprecedented ability to characterize exoplanetary atmospheres. While there are over 5000 confirmed planets, more than 4000 Transiting Exoplanet Survey Satellite (TESS) planet candidates are still unconfirmed and many of the best planets for atmospheric characterization may remain to be identified. We present a sample of TESS planets and planet candidates that we identify as “best-in-class” for transmission and emission spectroscopy with JWST. These targets are sorted into bins across equilibrium temperatureTeqand planetary radiusRpand are ranked by a transmission and an emission spectroscopy metric (TSM and ESM, respectively) within each bin. We perform cuts for expected signal size and stellar brightness to remove suboptimal targets for JWST. Of the 194 targets in the resulting sample, 103 are unconfirmed TESS planet candidates, also known as TESS Objects of Interest (TOIs). We perform vetting and statistical validation analyses on these 103 targets to determine which are likely planets and which are likely false positives, incorporating ground-based follow-up from the TESS Follow-up Observation Program to aid the vetting and validation process. We statistically validate 18 TOIs, marginally validate 31 TOIs to varying levels of confidence, deem 29 TOIs likely false positives, and leave the dispositions for four TOIs as inconclusive. Twenty-one of the 103 TOIs were confirmed independently over the course of our analysis. We intend for this work to serve as a community resource and motivate formal confirmation and mass measurements of each validated planet. We encourage more detailed analysis of individual targets by the community. 
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  9. Abstract Mature super-Earths and sub-Neptunes are predicted to be ≃ Jovian radius when younger than 10 Myr. Thus, we expect to find 5–15 R ⊕ planets around young stars even if their older counterparts harbor none. We report the discovery and validation of TOI 1227b, a 0.85 ± 0.05 R J (9.5 R ⊕ ) planet transiting a very-low-mass star (0.170 ± 0.015 M ⊙ ) every 27.4 days. TOI 1227's kinematics and strong lithium absorption confirm that it is a member of a previously discovered subgroup in the Lower Centaurus Crux OB association, which we designate the Musca group. We derive an age of 11 ± 2 Myr for Musca, based on lithium, rotation, and the color–magnitude diagram of Musca members. The TESS data and ground-based follow-up show a deep (2.5%) transit. We use multiwavelength transit observations and radial velocities from the IGRINS spectrograph to validate the signal as planetary in nature, and we obtain an upper limit on the planet mass of ≃0.5 M J . Because such large planets are exceptionally rare around mature low-mass stars, we suggest that TOI 1227b is still contracting and will eventually turn into one of the more common <5 R ⊕ planets. 
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